| Set | No. | Name | Rarity | |
|---|---|---|---|---|
| XY Black Star Promos | XY145 | Volcanion | Promo | |
| XY Black Star Promos | XY164 | Volcanion | Promo | |
| XY Black Star Promos | XY173 | Volcanion-EX | Promo | |
| XY Black Star Promos | XY185 | Volcanion | Promo | |
| Steam Siege | 25 | Volcanion | Rare | |
| Steam Siege | 26 | Volcanion-EX | Rare Holo EX | |
| Steam Siege | 107 | Volcanion-EX | Rare Ultra | |
| Steam Siege | 115 | Volcanion-EX | Rare Secret | |
| SM Black Star Promos | SM179 | Volcanion | Promo | |
| Shining Legends | 27 | Shining Volcanion | Rare Shining | |
| Shining Fates | 25 | Volcanion | Rare | |
| Chilling Reign | 25 | Volcanion V | Rare Holo V | |
| Chilling Reign | 162 | Volcanion V | Rare Ultra | |
| Crown Zenith | 26 | Volcanion | Rare Holo | |
| Paradox Rift | 22 | Volcanion | Rare | |
| Mega Evolution | 25 | Volcanion | Uncommon | |
| Perfect Order | 25 | Volcanion | Uncommon | |
| Forbidden Light | 31 | Volcanion ◇ | Rare Prism Star | |
| Journey Together | 31 | Volcanion ex | Double Rare | |
| Journey Together | 171 | Volcanion ex | Ultra Rare | |
| Journey Together | 182 | Volcanion ex | Special Illustration Rare | |
| Unbroken Bonds | 25 | Volcanion | Rare Holo | |
| XY Promos | XY145 | Volcanion (XY Steam Siege Prerelease) | Promo |