| Set | No. | Name | Rarity | |
|---|---|---|---|---|
| Alter Genesis | 64 | Sylveon | Uncommon | |
| Eevee Heroes | 40 | Sylveon V | Double Rare | |
| Eevee Heroes | 41 | Sylveon VMAX | Triple Rare | |
| Eevee Heroes | 82 | Sylveon V | Super Rare | |
| Eevee Heroes | 83 | Sylveon V | Super Rare | |
| Forbidden Light | 61 | Sylveon | Uncommon | |
| GX Battle Boost | 73 | Sylveon GX | Double Rare | |
| Night Unison | 31 | Gardevoir & Sylveon GX | ||
| Night Unison | 60 | Gardevoir & Sylveon GX | ||
| Night Unison | 61 | Gardevoir & Sylveon GX | ||
| Night Wanderer | 22 | Sylveon | ||
| Pokekyun Collection | 25 | Sylveon EX | Double Rare | |
| Pokekyun Collection | 26 | Sylveon EX | Double Rare | |
| Rising Fist | 67 | Sylveon | Rare | |
| Scarlet & Violet Promos | 70 | Sylveon | Common | |
| Start Deck 100 | 191 | Sylveon V | ||
| Start Deck 100 | 192 | Sylveon VMAX | ||
| Sun & Moon Promos | 323 | Sylveon GX | ||
| Sun & Moon Strengthening Expansion | 40 | Sylveon GX | Double Rare | |
| Sun & Moon Strengthening Expansion | 57 | Sylveon GX | Super Rare | |
| Terastal Festival ex | 68 | Sylveon | Common | |
| Terastal Festival ex | 69 | Sylveon ex | Double Rare | |
| Terastal Festival ex | 212 | Sylveon ex | Special Art Rare | |
| Ultra Shiny GX | 238 | Sylveon GX | Shiny Secret Rare | |
| VMAX Climax | 74 | Sylveon V | Double Rare | |
| VMAX Climax | 75 | Sylveon VMAX | Triple Rare | |
| VMAX Climax | 231 | Sylveon V | Character Super Rare | |
| VMAX Climax | 232 | Sylveon VMAX | Character Super Rare |