| Set | No. | Name | Rarity | |
|---|---|---|---|---|
| Hidden Legends | 12 | Milotic | Rare Holo | |
| Emerald | 8 | Milotic | Rare Holo | |
| Emerald | 96 | Milotic ex | Rare Holo EX | |
| Dragon Frontiers | 5 | Milotic δ | Rare Holo | |
| Great Encounters | 25 | Milotic | Rare | |
| Supreme Victors | SH7 | Milotic | Rare | |
| Supreme Victors | 35 | Milotic C | Rare | |
| Supreme Victors | 70 | Milotic | Uncommon | |
| Dragons Exalted | 28 | Milotic | Rare Holo | |
| Primal Clash | 44 | Milotic | Rare Holo | |
| Crimson Invasion | 27 | Milotic | Rare Holo | |
| Dragon Majesty | 29 | Milotic | Uncommon | |
| Rebel Clash | 43 | Milotic V | Rare Holo V | |
| Rebel Clash | 179 | Milotic V | Rare Ultra | |
| Darkness Ablaze | 39 | Milotic | Rare Holo | |
| Evolving Skies | 38 | Milotic | Rare | |
| Silver Tempest | 40 | Milotic | Rare | |
| Silver Tempest Trainer Gallery | TG02 | Milotic | Trainer Gallery Rare Holo | |
| Paradox Rift | 36 | Milotic | Rare | |
| Destined Rivals | 53 | Cynthia's Milotic | Uncommon | |
| Flashfire | 23 | Milotic | Rare Holo | |
| Surging Sparks | 42 | Milotic ex | Double Rare | |
| Surging Sparks | 217 | Milotic ex | Ultra Rare | |
| Surging Sparks | 237 | Milotic ex | Special Illustration Rare | |
| Twilight Masquerade | 50 | Milotic | Uncommon |