| Set | No. | Name | Rarity | |
|---|---|---|---|---|
| Scarlet & Violet Black Star Promos | 68 | Iron Valiant ex | Promo | |
| Paradox Rift | 89 | Iron Valiant ex | Double Rare | |
| Paradox Rift | 225 | Iron Valiant ex | Ultra Rare | |
| Paradox Rift | 249 | Iron Valiant ex | Special Illustration Rare | |
| Paradox Rift | 261 | Iron Valiant ex | Hyper Rare | |
| Temporal Forces | 79 | Iron Valiant | Uncommon | |
| Temporal Forces | 79 | Iron Valiant Cosmo Holo | Uncommon | |
| Temporal Forces | 80 | Iron Valiant | Rare | |
| Prismatic Evolutions | 157 | Iron Valiant ex | Special Illustration Rare |