| Set | No. | Name | Rarity | |
|---|---|---|---|---|
| Diamond & Pearl | 4 | Empoleon | Rare Holo | |
| Diamond & Pearl | 120 | Empoleon LV.X | Rare Holo LV.X | |
| DP Black Star Promos | DP11 | Empoleon LV.X | Promo | |
| Majestic Dawn | 17 | Empoleon | Rare | |
| Stormfront | 2 | Empoleon | Rare Holo | |
| Platinum | 26 | Empoleon | Rare | |
| Supreme Victors | 27 | Empoleon FB | Rare | |
| BW Black Star Promos | BW56 | Empoleon | Promo | |
| Dark Explorers | 29 | Empoleon | Rare Holo | |
| Plasma Freeze | 117 | Empoleon | Rare Secret | |
| XY Black Star Promos | XY134 | Empoleon BREAK | Promo | |
| Legendary Treasures | 35 | Empoleon | Rare | |
| BREAKthrough | 38 | Empoleon | Rare Holo | |
| Ultra Prism | 34 | Empoleon | Rare | |
| SWSH Black Star Promos | SWSH108 | Empoleon V | Promo | |
| Battle Styles | 40 | Empoleon V | Rare Holo V | |
| Battle Styles | 145 | Empoleon V | Rare Ultra | |
| Battle Styles | 146 | Empoleon V | Rare Ultra | |
| Brilliant Stars | 37 | Empoleon | Rare Holo | |
| Phantasmal Flames | 70 | Empoleon ex | Double Rare | |
| Phantasmal Flames | 114 | Empoleon ex | Ultra Rare | |
| Cosmic Eclipse | 56 | Empoleon | Rare | |
| Forbidden Light | 81 | Empoleon | Rare Holo | |
| Jumbo Cards | XY134 | Empoleon BREAK - XY134 (XY Black Star Promos) |